全文获取类型
收费全文 | 11842篇 |
免费 | 1281篇 |
国内免费 | 792篇 |
专业分类
电工技术 | 2594篇 |
综合类 | 1027篇 |
化学工业 | 688篇 |
金属工艺 | 857篇 |
机械仪表 | 821篇 |
建筑科学 | 167篇 |
矿业工程 | 187篇 |
能源动力 | 256篇 |
轻工业 | 204篇 |
水利工程 | 87篇 |
石油天然气 | 284篇 |
武器工业 | 270篇 |
无线电 | 3480篇 |
一般工业技术 | 1137篇 |
冶金工业 | 251篇 |
原子能技术 | 444篇 |
自动化技术 | 1161篇 |
出版年
2024年 | 13篇 |
2023年 | 95篇 |
2022年 | 169篇 |
2021年 | 246篇 |
2020年 | 262篇 |
2019年 | 222篇 |
2018年 | 234篇 |
2017年 | 398篇 |
2016年 | 452篇 |
2015年 | 517篇 |
2014年 | 675篇 |
2013年 | 706篇 |
2012年 | 899篇 |
2011年 | 1009篇 |
2010年 | 758篇 |
2009年 | 754篇 |
2008年 | 813篇 |
2007年 | 952篇 |
2006年 | 811篇 |
2005年 | 679篇 |
2004年 | 505篇 |
2003年 | 472篇 |
2002年 | 376篇 |
2001年 | 330篇 |
2000年 | 241篇 |
1999年 | 225篇 |
1998年 | 170篇 |
1997年 | 172篇 |
1996年 | 149篇 |
1995年 | 121篇 |
1994年 | 114篇 |
1993年 | 89篇 |
1992年 | 61篇 |
1991年 | 54篇 |
1990年 | 46篇 |
1989年 | 35篇 |
1988年 | 24篇 |
1987年 | 14篇 |
1986年 | 15篇 |
1985年 | 16篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 8篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1959年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
Tomasz Pdzinski Katarzyna Grzyb Konrad Skotnicki Piotr Filipiak Krzysztof Bobrowski Chryssostomos Chatgilialoglu Bronislaw Marciniak 《International journal of molecular sciences》2021,22(9)
Within the reactive oxygen species (ROS) generated by cellular metabolisms, hydroxyl radicals (HO•) play an important role, being the most aggressive towards biomolecules. The reactions of HO• with methionine residues (Met) in peptides and proteins have been intensively studied, but some fundamental aspects remain unsolved. In the present study we examined the biomimetic model made of Ac-Met-OMe, as the simplest model peptide backbone, and of HO• generated by ionizing radiation in aqueous solutions under anoxic conditions. We performed the identification and quantification of transient species by pulse radiolysis and of final products by LC-MS and high-resolution MS/MS after γ-radiolysis. By parallel photochemical experiments, using 3-carboxybenzophenone (CB) triplet with the model peptide, we compared the outcomes in terms of short-lived intermediates and stable product identification. The result is a detailed mechanistic scheme of Met oxidation by HO•, and by CB triplets allowed for assigning transient species to the pathways of products formation. 相似文献
3.
通过对AAOA-MBR工艺在实际工程中的应用,分析该工艺处理城市污水的节能减排效能。实践表明AAOA-MBR工艺具有很强的抗冲击负荷能力,在进水质水量大幅度波动、且碳源匮乏的情况下,仍能取得良好的处理效果。实际工程运行四年来,厂区出水各项指标均稳定优于城镇污水处理厂污染物排放标准(GB 18918-2002)中的一级A标准,其中COD、BOD5、SS、NH3-N去除率分别达到可分别达到90.14%、98.25%、95.58%和98.2%;通过对运行期间污水处理量与耗电量相关关系进行回归分析可知,当处理水量达到设计规模时,其吨水耗电量预测为0.31kWh/m3。同时,基于对污水处理系统的沿程水质检测,优化进水水量分配和内循环回流比并进行产水泵联动改造,可进一步提高系统节能减排效果。 相似文献
4.
周期性隔震基础是利用周期性结构的衰减域特性,将地震动与上部结构自振频率接近的频率范围内的能量衰减,从而控制上部结构响应的新型隔震装置。周期性基础的隔震性能受到多方面因素的影响,包括局域共振子的调谐频率比、质量比、阻尼比、基体的刚度、上部结构与基础的相互作用以及地震动的频谱特性等。目前尚未有研究综合考虑上述因素的影响并提出周期性基础的设计方法。提出以一组地震动作用下上部结构峰值响应衰减率的平均值为目标函数,对周期性基础进行优化的设计方法。计算结果表明,按照该优化方法得到的周期性基础对上部结构在选取的44条地震动作用下,峰值响应的平均衰减率达30%。参数敏感性分析表明,优化设计得到的周期性基础对于自身参数的变化具有良好的鲁棒性。最后利用缩尺振动台试验验证了优化设计得到的周期性基础的隔震性能,证明了优化方法的有效性和优化结果的正确性。 相似文献
5.
《低温学》2018
A Stirling/pulse tube hybrid cryocooler (SPC), comprised of a Stirling cryocooler as the first stage and a pulse tube cryocooler as the second stage, features the ability of shifting cooling capacity between stages by adjusting the movement of the displacer in the first stage. Such an ability allows an SPC to accommodate itself to time-varying heat loads at different temperatures, which makes it a competitive candidate in space applications. However, due to the gas coupling, there exists a significant mutual effect between stages which endows an SPC with special thermodynamic characteristics and has a significant effect on the SPC’s capability of shifting cooling capacity between stages. With the phasor analysis and the thermodynamic analysis, this paper establishes an idealized model of an SPC. The model is then used to study the effect of the second stage on the first stage and reveal the condition that an SPC is able to shift cooling capacity between stages. Also, the model is compared with a Sage numerical model and the two models are consistent on the overall trend. Though it is unable to reflect reality precisely, the idealized model can interpret the mechanism and highlight some of the essential nature of an SPC, which will eventually benefit the appropriate design of an SPC. 相似文献
6.
7.
采用SPM (Sulfuric-Peroxide Mixtures, 98wt%H2SO4+30wt%H2O2)+兆声(方法1)和氧等离子体+HPM (Hydrochloric/Peroxide Mixture, 37wt%HCl+30wt%H2O2+DIH2O)+兆声(方法2)两种清洗方法对多层介质膜脉宽压缩光栅进行清洗, 并对清洗前后样品的表面元素含量、衍射效率、表面粗糙度、表面温升以及激光损伤阈值等参数进行测量以评估两种清洗方法清洗效果。在入射角70°, 脉宽12 ns, s偏振, 波长1064 nm的激光辐照下, 经过清洗方法1清洗后的光栅样品单脉冲激光损伤阈值为7.55 J/cm 2, 而方法2清洗后的样品损伤阈值为5.32 J/cm 2。另外, 虽然经过方法2清洗后样品表面杂质含量更低, 但是在衍射效率、表面粗糙度和表面温升都劣于经方法1清洗后的样品, 进一步分析发现方法2中氧等离子体清洗过程引入的Fe元素影响了其样品损伤性能和温升性能。因此, SPM清洗方法可以作为多层介质膜脉宽压缩光栅提升抗激光损伤性能的优化清洗方案。 相似文献
8.
《中国有色金属学会会刊》2021,31(12):3800-3813
The Fe−Ni−TiO2 nanocomposite coatings were electrodeposited by pulse frequency variation. The results showed that the nanocomposite with a very dense coating surface and a nanocrystalline structure was produced at higher frequencies. By increasing the pulse frequency from 10 to 500 Hz, the iron and TiO2 nanoparticles contentswere increased in expense of nickel content. XRD patterns showed that by increasing the frequency to 500 Hz, an enhancement ofBCC phase was observed and the grain size of deposits was reduced to 35 nm. The microhardness and the surface roughness were increased to 647 HV and 125 nm at 500 Hz due to the grain size reduction and higher incorporation of TiO2 nanoparticles into the Fe−Ni matrix (5.13 wt.%). Moreover, the friction coefficient and wear rate values were decreased by increasing the pulse frequency;while the saturation magnetization and coercivity values of the composite deposits were increased. 相似文献
9.
A new method is described, in which 3D‐printed structures are implemented in bubble column reactors to dissolve the macroscopic and the microscopic influences. The effect of these structuring method on the fluid dynamic behavior, the gas distribution, mass transfer, and fluid velocity inside bubble columns is shown in this contribution. 相似文献
10.